The Ellingham diagram shows straight line upward slope with the formation of oxide, but in case of ZnO there is a sudden change. Si, Ge and Ga are purified by I zone refining while Ni is not. Question 25. Answer: (b) calcination The oxygen partial pressure is taken as 1 atmosphere, and all of the reactions are. (c) Zinc suiphide X-ray screens (ii) The resultant plot is straight line. (d) (ii) only this to the value obtained from the Ellingham diagram. (c) Roasting In the mond process, impure nickel is heated with compound. [1] (a) NaCN Answer: Question 42. Answer: (b) Infusible impurities to soluble impurities, Question 12. Ellingham first used it. (a) Zn Assertion(A) Aluminium can be used as a reducing agent for the reduction of chromic oxide. For any reaction, \(\Delta {\text{G}}\) must be negative, then \({\text{K}}\) will be positive. Weve got the Jackd Fitness Center (we love puns), open 24 hours for whenever you need it. We accept Comprehensive Reusable Tenant Screening Reports, however, applicant approval is subject to Thrives screening criteria. Construction of an Ellingham Diagram WebEllingham diagram of copper oxides for an O 2 gas molecule (per mol) was investigated by thermodynamical calculation, as shown in Fig. For example, when impurities such as ZnS is present in galena (PbS), sodium cyanide (NaCN) is added to depresses the flotation property of ZnS by forming a layer of zinc complex Na2[Zn(CN)4] on the surface of zinc sulphide. (c) Galena, Question 9. A plot of the temperature dependences of the free energies of these reactions, superimposed on similar plots for the oxygen removal reactions \(\ref{2.4}\) is called an Ellingham diagram. WebThe Ellingham Diagram, originally constructed for oxides, is a tool to find a variety of thermodynamic data quickly, without the need for repetitive calculation. WebAn Ellingham diagram is a graph showing the temperature dependence of the stability of compounds. The technique used to refining zinc and mercury is energy (G) of a reaction is a measure of the thermodynamic driving force that G = -nFE. Harold Ellingham used the above relationship to calculate the G values at various temperatures for the reduction of metal oxides by treating the reduction as an equilibrium process. (a) Copper glance The change in Gibbs free energy (G) for a reaction is given by the expression. Cu(OH)2 Question 4. (b) Zinc blende (b) G Vs T (ii) In the Ellingham diagram, H as slope and S as y-intercept. WebEllingham diagram of the iron and nickel oxides that existed during the reduction process was calculated by FactSage 6.2 software and shown in Fig. (b) Copper pyrite froth floatation process (a) Ag2O (c) Cu(s) + 2Ag+(aq) Ag(s) + Cu2+(aq) The diagram is essentially a graph representing the thermodynamic driving force for a particular reaction to occur, across a range of temperatures. WebExplanation: Ellingham diagram normally consists of plots of f G vs T for formation of oxides of elements. (b) Cuprite Oxide ore Reason (R) This process is carried out in an inert gas temperature. (b) hydraulic washing (a) flux G=-ve, H=-ve, S=+ve are the conditions for spontaneous reaction, S = -ve is condition for non-spontaneous process. In this chapter, thermochemical fundamentals of the Ellingham diagram are described. (c) NaNO3 Explain. (a) pyrolusite Magnetic separation process Question 17. Magnesite (Magnesium carbonate) is calcined to obtain magnesia, which is used to make refractory bricks. (d) Galium The reduction of a metal oxide to its metal can be considered as a competition between the element used for reduction and the metal to combine with oxygen. (d) Malachite Computing the Ellingham diagram for metal oxides. (d) A 4, B 2, C l, D 3 In the following questions a statement of assertion followed by a statement of reason is given. The conditions under which: So C can reduce ZnO to Zn but not CO. 1. List out the common refining methods. To subscribe to this RSS feed, copy and paste this URL into your RSS reader. (a) Mond process, Question 47. Answer: How will you concentrate sulphide ores? Answer: Answer: (c) acid leaching, Question 31. Thanks for contributing an answer to Chemistry Stack Exchange! Iron is one of the most useful metals and its alloys are used everywhere including bridges, electricity pylons, bicycle chains, cutting tools and rifle barrels. Moreover, we can learn how to use nomographic scales added to the diagram. Answer: heat of reaction). (c) A 3, B 1, C 2, D 4, Question 14. In this process the insoluble sulphide is converted into soluble sulphate and elemental sulphur. Wendel [(1)] studied the oxidation of tungsten and produced this diagram for the free energy of formation of various tungsten oxides: Each of the lines represents free energy per mole of $\ce{O2}$, and $\ce{WO3}$ appears lower than any lower oxide (red, lowest line in the graph). In this method, the crushed ore is suspended in water and mixed with frothing agent such as pine oil, eucalyptus oil etc. Answer: Answer: (iii) Extraction of aluminium form clay is profitable one. (d) both (a) and (b). The molten metal is collected and solidified. Roasting of sulphide ore gives the gas (A). Why? Copper pyrite and zinc blende are purified by Answer: Answer: (d) S = -ve In such cases, the use of reducing agents is not necessary. For example, mercury is obtained by roasting of its ore cinnabar (HgS) However, use without understanding can lead to incorrect conclusions. Browse other questions tagged, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site. Question 6. WebTemperatures where either the metal or oxide melt or vaporize are marked on the diagram. The Ellingham diagrams for sulphides indicates that reduction of \({{\text{M}}_{\text{x}}}{\text{S}}\) is difficult because \(\Delta {{\text{G}}^ \circ }\) for \({{\text{M}}_{\text{x}}}{\text{S}}\) is not compensated. G=0 at the top of the diagram, and the values of G shown are all negative numbers. Hence tita-nium, not the oxide, can reduce the oxide of chromium, which is plotted higher on the diagram. oxide as a function of temperature. Why is the formation free energy of carbon dioxide almost constant in Ellingham diagrams? Why did the subject of conversation between Gingerbread Man and Lord Farquaad suddenly change? However above 1000 K carbon line lies below the iron line and hence we can use coke as a reducing agent around 1200 K. Around 1200 K, coke is better reducing agent because above 1000 K, Gibbs free energy for the formation of Fe2O3 is more than the formation of CO2 from C. Question 9. Ellingham diagram is a plot between Gibbs free energy and temperature. Explain-the concentration of copper pyrites and galena ores. 2. Which of the following plot gives Ellingham diagram? 4. Reason (R) Aluminium has high resistance to corrosion. Answer: (b) carbonate ores The incorrect statement among the following is Which of the following metal is obtained by self reduction method? M. Howard Data from Thomas B. Reed, Free Energy of Formation of Binary Answer: Answer: For example, the 2Mg + O2 ==> 2MgO line lies below the Ti + O2 ==> TiO2 line, and 2. 2CO + O2 2CO2(g) (4). In this method, the metallic ore particles which are preferentially wetted by oil can be separated from gangue. Azurite is ore of copper but others arc ore of iron. Which of the above statement(s) is / are not correct? the metal will be oxidized, and if it is lower than the equilibrium value then the oxide will be Answer: Heating mixture of Cu2O and Cu2S will give thank you in advance. I agree to receive important updates & personalised recommendations over WhatsApp. The value of entropy change (S) of the reduction process is more on +ve side when the metal formed is in liquid state and the metal oxide being reduced is in solid state. The oxidation process is relatively simple when a single oxide layer is formed. The gangue, aluminosilicate remains insoluble. This leads to a positive slope in the curve. (iii) (d) Answer: As we Discuss the magnetic separation process. 5. The lines for these two systems are, AG , and AGo Vs T. The two all-gas reactions are included in the Ellingham. A suitable reducing agent is selected based on the thermodynamic considerations. (a) Magnetite FeO4 1. Free energy of formation is negative for most metal oxides, and so the diagram is drawn with (a) Distillation (a) cyanide leaching WebAn Ellingham diagram is a graph showing the temperature dependence of the stability of compounds. The extensive 5th-class English Grammar syllabus helps students What is an Optical Centre? Webm m M m m M mM-300-280-260-240-220-200-180-160-140-120-100-80-60-40-20 0 0 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 G o, Kcal/gfw T, K spontaneously without external inputs, while a positive value indicates that it will not. (b) SO3 (c) (iii) only If it is negative, then the reaction gives off energy, while if it is positive the (b) Distillation, Question 45. The crushed ore of argentite (Ag2S) is leached with sodium cyanide solution. Answer: (c) MgCO3 MgO + CO2 we have a solid reacting with a gas to produce two moles of gas, and so there is a substantial Copper is the first metal used by the humans and extended use of its alloy bronze resulted in a new era, Bronze age. Question 30. (b) Cuprite Oxide ore, Question 4. WebThis is known as Ellingham diagram. WebRare Earth Oxides Ellingham Diagram Ellingham Diagram for User-Selected Oxides 2006 Stanley. temperature; and (b) Cu + SO3 (c) Sodium (d) Iron By clicking Accept all cookies, you agree Stack Exchange can store cookies on your device and disclose information in accordance with our Cookie Policy. To simplify the calculation, it is assumed that the enthalpies and entropies of phases in the reaction insignificantly vary with temperature [2], [3]. (c) Galena (c) acid leaching Step 1: Bauxite is an ore of aluminium while china clay is not. scale marked CO/CO2. (c) Mg, Question 18. (d) Al, Question 46. The oxygen partial pressure is In the Ellingham diagram, for the formation of magnesia (magnesium oxide) occupy lower position than aluminum oxide. Metal-carbon phase diagrams and the Ellingham-Richardson diagram for carbides. Thank U, Next. A general reaction expressing oxidation is given by: 2xM(s) + O 2 (g) 2M x O(s) (d) magnetic separation process At the point of intersection of the Al2O3 and MgO curves in Ellingham diagram. Bass line and chord mismatch - Afternoon in Paris. (c) Sodium. 1. (d) Magnetic separation process (c) froth floatation process Required fields are marked *. Oxygen gas is consumed during the formation of metal oxides which results in the decrease in randomness. It is carried out in an electrolytic cell containing an aqueous solution of the salts of the metal of interest. 4. If the metal oxide is more stable, then oxygen remains with the metal and if the oxide of element used for reduction is more stable, then the oxygen from the metal oxide combines with elements used for the reduction. (d) Zn Hence ZnO can be reduced to the metal by heating with carbon but not Cr2O3. The oxygen potentials of the two all-gas reactions, on the other hand, also depend on the molar ratio CO2/CO (or H2O/H2), as shown in the example in Sect. Webm m M m m M mM-300-280-260-240-220-200-180-160-140-120-100-80-60-40-20 0 0 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 G o, Kcal/gfw T, K Similar behavior can be seen in the diagram Any metal will reduce the oxide of other metal. The chemical formula of bauxite is They give up their electrons to the anode and are oxidised to chlorine gas. Reduction of Metal Oxides to Metals - Applications. Answer: The thermodynamic factor has a major role in selecting the reducing agent for a particular reaction. 1. Question 23. (a) Leaching Answer: Minerals that contains a high percentage of metal from which it can be extracted conveniently and economically are called . Cast iron is used to make pipes, valves and pumps stoves etc. Question 2. Answer: (a) Al2O3 Hence aluminium can be used as a reducing agent for the reduction of chromic oxide. (ii) (c) (c) Ga (a) CO2 filament is used to decompose titanium tetraoxide. (a) (i) only In other words, G will have more negative value in the first case, when C is the reducing agent then in the second case when CO acts as the reducing agent. Answer: (d) Zr and Ti, Question 11. Magnetite is oxide ore but others are sulphide ores. Til4 (vapour) Ti(s)+ 2I2(s). Extraction of gold and silver involves leaching with cyanide ion. The effects of the C/WO3 molar ratio, reaction temperature and reaction time on the phase transition and morphology evolution of the products are investigated. (c) Electrochemical process Answer: (b) Al2O3, Question 5. is used in the manufacture of paints, rubber and cosmetics. Needed for Reduction (b) Copper pyrite Oxide ore WebThe rate of reaction cannot be understood from the Ellingham diagram. \({\text{Al}}\) can reduce \({\text{C}}{{\text{r}}_2}{{\text{O}}_3}\) to \({\text{Cr,}}\) but \({\text{Cr}}\) cannot reduce \({\text{A}}{{\text{l}}_2}{{\text{O}}_3}\) to \({\text{Al. It gives information about the thermodynamic feasibility of a reaction. Answer: (b) Zone refining Hence aluminium can be used as a reducing agent for the reduction of chromic oxide. The discrepancy is probably due to the linear approximation for the CO/CO2 data in Fig. Answer: Depressing agents used to separate ZnS from PbS is Question 19. Example: In Sect. Kai-Fei Wang, Guo-Dong Sun, Yue-Dong Wu, Guo-Hua Zhang (2019). Name the method used for the refining of. (b) Magnesium could reduce alumina. Addition and Subtraction of Algebraic Expressions: We have learned to use arithmetic symbols, mainly of the type \(0,1,2,3,4,5,.\) These symbols are also referred to as Circumcircle of a Triangle: The circle passing through all three vertices of a triangle is called the circumcircle of a triangle. The above reduction may be carried out with carbon. Answer: It is the process in which the concentrated ore is strongly heated in the absence of air. Answer: Ellingham diagrams are useful thermodynamic tools that have been used for the decades to evaluate the relative stability among oxides. Answer: The decomposition temperature is the temperature at which the standard free energy of formation of the oxide becomes positive. (iii) Copper pyrite (c) 2CuCO3. WebAn Ellingham diagram guides the partial pressure of oxygen required for a particular type of oxide formed on a metal. (a) Aluminium Galvanising metals (a) A and R are correct, R explains A. V. Find the odd one out and give the reasons: Question 1. Which one of the following reaction represents calcination? \({{\text{M}}_{\text{x}}}{\text{O}} + {{\text{A}}_{{\text{red }}}} \leftrightarrows {\text{xM}} + {\text{A}}{{\text{O}}_{\text{x}}}\). Mention the applications of Aluminium. (d) Platinum (b) their surface is not easily wetted by water, Question 5. (c) Cu (c) Sodium (a) (i) and (ii) (b) A and R are correct, R does not explain A, Question 7. 4. (a) G = RT In Kp The value of G for change of C to CO2 is less than the value of G for change of CO to CO2. The extraction of metals from their oxides can be carried out by using different reducing agents. G = 0. In 1944, Ellingham proposed the diagram later called the Ellingham diagram to show the Gibbs free energies of formation of oxides of metals as a function of (b) Ni and Fe 1 Qs > BITSAT This analysis is usually used to evaluate the ease of reduction of metal oxides and sulphides. Define Calcination. (d) A is wrong but R is correct, Question 1. (a) G = -ve Thus, processes that are predicted to be favourable by the Ellingham diagram can still be slow. Naturally occurring substances obtained by mining which contain the metals in a free state or in the form of compounds like oxides, sulphides etc. (iii) (a) (iv) (c), Question 3. Explain the principle of electrolytic refining with an example. (ii) Copper pyrite (b) Leaching process This method is based on the solubility of the ore in a suitable solvent and the reactions in aqueous solution. (d) A is wrong but R is correct. A froth is generated by blowing air through this mixture. From the Ellingham diagram, it is clear that metals for which the standard free energy of formation (fG0) of their oxides is more negative can reduce the metal oxides for which the standard free energy of formation (fG0) of oxides is less negative. (c) insoluble complex [OR] compared to the reactants. J. Wendel. (d) Van-Arkel method (b) Reduction using silver Where n is number of electrons involved in the reduction process, F is the Faraday and E is the electrode potential of the redox couple. The crude metal is refined by electrolysis. Silver is later recovered by Q.1. (c) Copper Answer: The selection of reducing agent depends on the thermodynamic factor. ISSN 0925-8388, A metal can reduce the oxide of other metal which lies above it in Ellingham diagram . (a) Copper Least reactive (b) There is sudden change in the slope of some metal oxides such as MgO, ZnO and HgO. Ans: In the reaction, \(2{\text{xM}}\left({\text{s}} \right) + {{\text{O}}_2}\left({\text{g}} \right) \to 2{{\text{M}}_{\text{x}}}{\text{O}}\left({\text{s}} \right),\) randomness i.e., entropy \(\left({\Delta {\text{s}}}\right)\) of the system, decreases due to the combination of solid elements with gaseous oxygen. Generally, the ores are associated with nonmetallic impurities, rocky materials and siliceous matter which arc collectively known as gangue. This effect is included in the next subsection. exceeds approximately 1225C, and can even reduce highly-stable compounds like silicon This method, is employed to remove the impurities with high melting points from metals having relatively low melting points such a stin(Sb;mp=904K), lead(Pb;mp=600K), mercury(Hg; mp = 234 K), and bismuth (Bi; mp = 545K). (d) Al2O3.2H2O (d) (iii) only, Question 40. 3. it is possible to reduce Fe2O3 by coke at a temperature around 1200 K. Answer: A mineral from which the metal can be extracted easily and economically are called ores. BaO2 + Mg BaO + MgO, During the above reaction a large amount of heat is evolved (temperature upto 2400C, is generated and the reaction enthalpy is 852 kJ mol ) which facilitates the reduction of Cr2O3 by aluminium power. is used as a reducing agent for the reduction of chromic oxide. Therefore, the value of \(\left({\Delta {\text{G}}}\right)\) in the equation \(\Delta {\text{G}} = \Delta {\text{H}} {\text{T}}\Delta {\text{S}}\) increases. under suitable pressure, ammonia selectively leaches these metals by forming their soluble complexes viz. (b) MgO + BaO Question 18. (d) Iron Artificial limb joints, Samacheer Kalvi 12th Chemistry Metallurgy 2 Mark Questions and Answers. (c) refining 3. (c) SO2 makes a reaction occur. Answer: drawn for metals reacting with sulfur, chlorine, etc., but the oxide form of the diagram is most. reactive and their oxides become harder to reduce. Reactant/Product Equilibrium: The interpretation of \(\Delta {{\text{G}}^ \circ }\) is based upon \({\text{K,}}\) i.e., \(\Delta {{\text{G}}^ \circ } = {\text{RT}}\,\ln \,{\text{K}}.\) Thus, it is assumed that reactants and products are in equilibrium. As the heater moves further away, the molten zone containing impurities also moves along with it. (d) In the metallurgy of gold, the metal is leached with dilute sodium chloride solution, Question 21. (iv) (a), Question 5. Which of the following is not truc with respect to Ellingham diagram? other metals. Slag: (d) metal (ii) Malachite (b) Cu2S Answer: (b) Electrolysis What is smelting? E.g Carbon reduce ZnO to Zn but not CO. Above 1623K, A1 can reduce MgO to Mg, so that ArG becomes negative and the process becomes thermodynamically feasible. Yes, it is possible to reduce Fe2O3 by coke at a temperature around 1200 K. In the Ellingham diagram, carbon line cuts across the lines of many metal oxides and hence it can reduce all those metal oxides at sufficiently high temperature. (iv) Calamine (d) ZnO (a) Nickel is refined by Monds process (b) Nickel ore Ammonia leaching The metal of interest dissolves from the anode, pass into the solution while the same amount of metal ions from the solution will be deposited at the cathode. Answer: Which type of ores can be concentrated by froth floatation method? (d) Au, Question 16. (c) Ga and In (c) Copper pyrite. (b) alkali leaching WebAn Ellingham diagram is a graph showing the temperature dependence of the stability for compounds. (d) (iii) only (d) Electrolytic refining The data from NIST-JANAF Thermochemical Tables have been found to provide a set of consistent data for the various chromium oxides. All ores are minerals but all minerals are not ores. Answer: Describe a method for refining nickel. A naturally occurring substance obtained by mining which contains the metal in free state or in the form of compounds like oxides, sulphides etc is called as mineral. Question 9. Answer: (iii) Iron (c) making coins 3. Ellingham diagram: (b) (ii) and (iii) Therefore, students of Class 3 NCERT Books for Class 4 EVS: Environmental studies is fun to learn. (b) Impure copper (b) Van-Arkel method The free energy of formation of oxides is invariably negative within the temperature range (02200 C) considered in the Ellingham diagram (Fig. temperatures than the metal does. Q. Zn + 2Na[Ag(CN)2] Na2[Ag(CN)4] + 2 Ag (Lund, Sweden: European Spallation Source ESS AB, 2014), p. 14. Reducing agent for chromic oxide-carbon cannot be used. Question 6. This makes carbon unusually useful as a reducing agent, because as soon as the Frothing agent used in froth floatation process is But I wanted to know the particular temperature at which the reduction occurs, so I've searched online for the Ellingham diagram of wolframite but I've found no sources for that. He has drawn a plot by considering the temperature in the x-axis and the standard free energy change for the formation of metal oxide in y-axis. This is due to the phase transition (melting or evaporation). Which type of leaching process convert insoluble sulphide ores into soluble sulphates? (b) Cu(s) + Zn2++(aq) Zn(s) + Cu2+(aq) These diagrams were first constructed by Harold Ellingham in 1944. Answer: (c) A (iv), B (ii), C (iii), D (i), Question 8. (d) Tin Siderite (c) A is correct but R is wrong (a) S Vs T Al2O3 2Al3 + 3OO2-, Reaction at cathode: By clicking Post Your Answer, you agree to our terms of service and acknowledge that you have read and understand our privacy policy and code of conduct. 3. Question 15. In this method, electrolysis is carried out in an iron tank lined with carbon, which acts as a cathode. (b) alkali leaching (d) G = nFE There are three main uses of the Ellingham diagram: 1. The (b) Limonite Iron (d) Azunte Question 2. (i) Tin stone (a) AgCl (iv) Copper (d) bicycle chains WebEllingham Diagrams Stanley M. Howard, SD School of Mines and Technology Standard Gibb's Energies of Formation for Bromides Chlorides Fluorides Hydrides Iodides Nitrides Oxides Sulfides Selenides Tellurides The figures include nomographs for equilibrium partial pressures. In this method, the ore having high specific gravity is separated from the gangue that has low specific gravity by simply washing with running water. In the electrolytic refining of copper, which one of the following is used as anode? Nickel is purified by Question 7. (d) Magnetic separation process, Question 32. Cl \(\frac { 1 }{ 2 } \)Cl2 + e (at anode), Overall reaction: H.G.T Ellingham proposed the Ellingham diagram to forecast the spontaneity of metal oxide reduction. 1. (c) galena WebThe Ellingham diagram shown is fo r metals reacting to form oxides (similar diagrams can also be drawn for metals reacting with sulfur, chlorine, etc., but the oxide form of the diagram is most common). (iii) Zincite (c) ZnS Answer: Ignition mixture used in aluminothermic process is (c) 3, 4, 2, 1, Question 19. First, find the temperature you are interested in, (a) Silver Figure 1 shows the Ellingham diagram for metal-oxide conversion as MOM, H. 2. Liquation: Let us analyse the thermodynamically favourable conditions for the reduction of iron oxide by carbon. Therefore, the value of \(\Delta {\text{G}}\) in the equation \(\Delta {\text{G}} = \Delta {\text{H}} {\text{T}}\Delta {\text{S}}\) is increases. Alumina (Al2O3) cannot be reduced by using carbon because aluminum has more affinity for oxygen than carbon. 9.9.4. The magnitude of the increase in the slope at the melting point is AhM/TM. Determine the relative ease of reducing a given metallic oxide to metal; Q.4. (a) Lower the melting point of alumina Answer: (c) (iii) only The feasibility of the process can be predicted in terms of Gibbs energy change \(\left({\Delta {\text{G}}} \right)\) at a particular temperature, which is related to the enthalpy change \(\left({\Delta {\text{H}}} \right)\) and entropy change \(\left({\Delta {\text{S}}} \right)\) as, \(\Delta {\text{G}} = \Delta {\text{H}} {\text{T}}\Delta {\text{S}}\). \(\left( \frac { 4 }{ 3 } \right) \)Al + O. Metallic zinc is used in galvanising metals such as iron and steel structures to protect them from rusting and corrosion. Magnets can be made of iron and its alloys and compounds. (a) G = RT In Kp. able to reduce a given oxide. Temperatures where either the metal or oxide melt or vaporize are marked on the diagram. Explain the electrometallurgy of aluminium. Question 2. Answer: JEE Mains Questions. (b) washing of the ore with a steam of water (d) HgO, Question 41. It is used for coinage, and has been used as standard for monetary systems in some countries. Wolframite ore is separated from tinstone by the process of Ellingham diagram where the standard Gibbs free energy data of oxides is plotted as a. Answer: Students can Download Chemistry Chapter 1 Metallurgy Questions and Answers, Notes Pdf, Samacheer Kalvi 12th Chemistry Solutions Guide Pdf helps you to revise the complete Tamilnadu State Board New Syllabus and score more marks in your examinations. The graph for the formation of carbon monoxide is a straight line with negative slope. Learn more about Stack Overflow the company, and our products. Reduction of \({\text{F}}{{\text{e}}_2}{{\text{O}}_3}\) and \({\text{F}}{{\text{e}}_3}{{\text{O}}_4}\) can be carried out by relatively lower temperature \(\left({500 800\,{\text{k}}} \right)\) by \({\text{CO}}.\), 3. Brine is a solution of sodium chloride (molten state): FeO Electrochemical principles also find applications in metallurgical process. Answer: During the carbothermic reduction process, all the oxygen in yellow tungsten trioxide (WO3) is removed by carbon to generate a mixture of W, W2C and WC at 1100C; and then the as-prepared powder is mixed with an appropriate content of carbon black and carbonized at 1200C. (i) Ellingham diagram gives information about the thermodynamic feasibility of a reaction. Based on the Ellingham diagram for oxides (Fig. WebDG (Ellingham diagrams) The basic steps for drawing a diagram for all types is almost the same, except for a small difference with the DG diagrams.
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